Cookie chemistry (2024)

What makes a chocolate chip cookie chewy? Or crisp, or crunchy?

Cookie chemistry.

Cookie chemistry (1)

The interaction between sugar and fat and flour, baking time and temperature – plus a large measure of experimentation done right in your own kitchen – is how to nail your favorite chocolate chip cookie texture.

Let me tell you up front: I'm devoted to simplicity in food prep, and that includes baking. I don't use a cookie cutter, braid bread dough (aside from a basic 3-strand), or decorate cakes.

I put my heart and soul and brain into everything I bake – but I also put those three entities into a zillion other things important to me: like family, friends, counseling women with health issues, and volunteering at various non-profits.

Cookie chemistry (2)

So I'm not fond of trying 87 different takes on a recipe to get it exactly right.

First, I see that as a waste of time; if you can get 95% of the way there in the first three tries, you're good.

And second, having been developing recipes for King Arthur Flour for over 25 years, I know that what comes out of my home kitchen won't be exactly what comes out of yours – even when you follow the recipe exactly as written. Your oven, pans, ingredients, and even your micro-climate and the weather affect what you bake.

So here's the deal: my goal with this post is to show you how to take a basic chocolate chip cookie recipe and give it the texture you prefer: light and crunchy; thin and crisp; or soft and chewy.

More words than you could shake a spatula at have been written about "the perfect chocolate chip cookie." But what is that elusive being, anyway?

Cookie chemistry (3)

Plain and simple, the perfect chocolate chip cookie is the one you love best. So we're going to start with my favorite chocolate chip cookie recipe and, with a few simple tweaks, give you options for potentially turning it into YOUR favorite chocolate chip cookie recipe – no matter which camp your textural preference falls in: crunchy, crisp, or chewy.

Here's your beginning formula. If your favorite cookie is one that's crisp around the edges and softer in the center, stop right here: this is the recipe for you.

2/3 cup light brown sugar, firmly packed
2/3 cup granulated sugar
1/2 cup unsalted butter, right from the fridge, or at room temperature
1/2 cup vegetable shortening
3/4 teaspoon salt
2 teaspoons vanilla extract
1/4 teaspoon almond extract, optional
1 teaspoon vinegar, cider or white
1 teaspoon baking soda
1 large egg
2 cups (8 1/2 ounces) King Arthur Unbleached All-Purpose Flour
2 cups semisweet chocolate chips

Note: For complete directions, see the recipe: Chocolate Chip Cookies. I'm providing you with just the ingredients and some suggested baking temperatures/times here.

Cookie chemistry (4)

How to make crunchy chocolate chip cookies.

1. Substitute 2/3 cup granulated sugar for the brown sugar.

2. Substitute 1/2 cup vegetable shortening for the butter.

3. Bake the cookies for 23 minutes in a preheated 325°F oven.

Cookie chemistry: Crunchiness in a cookie depends on a good balance of fat and dryness. Butter contributes milk solids and water to a cookie, both of which soften it. Brown sugar contributes molasses – again, a softener.

Using lower-moisture sugar (granulated) and fat (vegetable shortening), plus a longer, slower bake than normal, produces light, crunchy cookies.

Cookie chemistry (5)

That said, using a combination of butter and vegetable shortening (as in the original recipe), or even using all butter, will make an acceptably crunchy chocolate chip cookie. It won't be AS crunchy as an all-shortening cookie; but for those who eschew vegetable shortening, it's an option.

Cookie chemistry (6)

How to make crisp chocolate chip cookies.

1. Substitute 2/3 cup granulated sugar for the brown sugar.

2. Substitute 1/2 cup butter for the vegetable shortening.

3. Bake the cookies for 30 minutes in a 325°F oven.

Cookie chemistry (7)

Cookie chemistry: The difference between a crunchy and crisp cookie is thickness; we perceive thicker cookies as crunchy, thinner cookies as crisp.

The melting temperature of butter is lower than that of shortening. As they bake, butter-based cookies start to spread before their structure is set; while those made with shortening set before the shortening reaches its melting point.

The result? In this recipe, cookies made with butter (above, left) are wider, thinner, and crispier than those based on shortening (above, right).

In addition, baking these thin cookies several minutes longer than their shortening-based counterparts transforms their innate crunchiness into crispiness.

Cookie chemistry (8)

How to make soft/chewy chocolate chip cookies.

1. Substitute 1 cup brown sugar for the 2/3 cup brown sugar and 2/3 cup granulated sugar.

2. Substitute 1/2 cup butter for the 1/2 cup vegetable shortening

3. Bake the cookies for 14 minutes in a preheated 325°F oven.

Cookie chemistry: We're taking a 180° turn from our crunchy cookies, substituting higher-moisture brown sugar and butter for their lower-moisture counterparts: granulated sugar and vegetable shortening. That, plus a shortened baking time, yields a cookie that's soft and chewy all the way through.

You'll notice these cookies use less sugar than the original recipe, too. Why is that?

Cookie chemistry (9)

Because the less sugar you use, the less cookies will spread. Above is a mistake I made along the way: one batch of cookies I made had 50% less sugar than it should have. See the difference in spread? (Actually, I liked this 50% less sugar cookie; it tasted plenty sweet, and its butter flavor was more apparent).

Considering I was using all butter (for its extra moistness) in my soft/chewy cookies, I didn't want to use the full ration of sugar as well, fearing the cookies would spread too much.

Cookie chemistry (10)

Some sources call for using bread flour to yield a chewier cookie. I wanted to believe in this, I really did, but the three tests I did showed no difference in chewiness between cookies made with King Arthur Unbleached Bread Flour, and those made with King Arthur Unbleached All-Purpose Flour.

Cookie chemistry (11)

Corn syrup is also recommended by some for extra-chewy cookies. And while I tried adding 2 tablespoons corn syrup to the dough along with the substitutions listed above, I didn't like the result: somewhat glossy, unattractive cookies that had no more chew than their non-corn syrup brethren.

My co-blogger, Susan Reid, says corn syrup is the only way to make "bendy" cookies – but I'll leave that for a future post.

Cookie chemistry (12)

I baked a LOT of chocolate chip cookies over the course of several days in putting together this post. Let me share some additional takeaways with you:

• The chips ratio: My favorite ratio of chocolate chips to cookie is 1 cup chips for every cup of flour in the recipe. This yields a cookie with a generous amount of chips, but not one that seems more gooey chocolate than crunchy cookie.

• Chill out: I discovered awhile ago that letting cookie dough chill for 30 minutes before baking improves cookies' flavor and helps control their spread. I also know that a fully heated oven is critical to cookie success. So make your cookie dough; put it into the fridge; then turn on the oven. Thirty minutes later, your dough will be chilled and your oven fully preheated.

And while we're on the subject – use an in-oven thermometer. The preheating times on ovens are notoriously inaccurate. Only an in-oven thermometer will tell you, for sure, whether your oven's up to temperature and ready to bake.

• Bake a test batch: The perception of crunchy vs. crisp vs. chewy is due somewhat to each person's own personal perception. In addition, all ovens bake slightly differently.

The baking times I give here work for my oven, and yield cookies that I taste as crunchy, crisp, or chewy. To nail down your own baking times, bake just 3 or 4 cookies to start. Let them cool sufficiently for you to see if they're the texture you're after.

Yes, this seems wasteful, letting your hot oven sit empty while cookies are cooling enough to assess their texture. But how much more wasteful is it to make an entire batch of cookies and then, 20 minutes after they're out of the oven, you decide they're not the texture you were looking for?

Cookie chemistry (13)

• Parchment makes a difference: All of my tests were done using parchment-lined, light-colored aluminum baking sheets (including the disastrous first take on chewy cookies pictured above).

Cookies baked on parchment won't spread as much; and their bottoms won't brown (or potentially burn) as quickly. For the complete results of our parchment/no parchment cookie baking tests, see our post, the secret to perfectly browned cookies.

We've arrived at the end of our chocolate chip cookie journey. And I can hear many of you saying, "Yes, but my chocolate chip cookie recipe uses butter and brown sugar and makes the perfect crunchy chocolate chip cookie!"

I have no doubt you can make crisp cookies with butter and brown sugar, and soft cookies with vegetable shortening and white sugar. If you already have your own "perfect" chocolate chip cookie recipe – stick with it! Like so many good things in life, there's more than one way to skin a cat – or bake a chocolate chip cookie.

Cookie chemistry (2024)

FAQs

What is the chemistry of baking sugar cookies? ›

As the sugars break down, they caramelize and create that signature fresh-baked cookie odor. Then the proteins in the egg and flour succumb to the Maillard reaction. This reaction occurs when sugars and proteins are heated together, for delicious results. The Maillard reaction is responsible for cookies' toasty flavor.

What is cookie in physics? ›

Cookies as a Model for Fusion

Fusion occurs when heat is added to atoms, giving them enough energy to collide and stick together. In this case, the microwave will add the energy to heat the “atoms” (cookies).

What elements are in cookies? ›

The foundation of any cookie recipe consists of five types of ingredients: fat, sugar, flour, a rising agent, and a binding agent. Fat is added for flavor and controls how chewy or crunchy the cookie is. More fat = a chewier cookie, less fat = a crunchier cookie.

What is the basic chemistry of baking? ›

When the baking temperature reaches 300 degrees Fahrenheit, the sugar mixed into the batter reacts with the amino acids from the eggs, butter, and gluten. Both the proteins and the sugars break apart and recombine, forming new molecules that give the cake it's toasty aroma and rich golden brown color.

What happens chemically when you bake cookies? ›

Heat breaks the sucrose into the simple sugars glucose and fructose, giving each cookie a shiny, light brown crust. When you take the cookies out of the oven, the hot water gases in the cookie contract. The chemical changes that occurred during baking help the cookie keep its shape.

What are the 7 basic ingredients in all cookies? ›

To make cookies from scratch, you'll typically need ingredients like flour, sugar, butter, eggs, baking powder/soda, vanilla extract, and salt. Specific recipes may include additional ingredients like chocolate chips, nuts, or oats depending on the type of cookies you want to make.

What is the science behind baking? ›

Chemistry, as you mix different edible chemicals to create dough or batter, with tiny air bubbles trapped inside. Biology, as the culture of yeast provides carbon dioxide to make your bread rise. And physics, as those trapped gases expand and give the rise to the bakes.

What binds cookies together? ›

Flour is a binding agent that provides structure and determines the density of the cookie. The type of flour affects the overall texture of the cookie too. All-purpose flour is often used because of its versatility, bread flour adds more chew, and cake flours produce a softer texture, paler color, and less spread.

What is the cookie model in chemistry? ›

Thomson's model of an atom describes that the electrons are like the chocolate chip cookies which are spread in a sphere of positive charge, which is similar to the rest of the part of the cookie.

What is the chemistry of baking a biscuit? ›

The chemical leavening gases, CO2 and NH3, originate from the dissociation of sodium and ammonium bicarbonate. Next to water vapour, these produced gases create gas bubbles in the biscuit dough. The concentrations of the leavening agents and added salt lead to high ionic strength.

What does sugar do in cookies? ›

Sugar creates texture

Sugar easily binds with water, which accomplishes two main things. 1) It locks in moisture, keeping your baked goods from drying out; and 2) It inhibits the development of gluten which keeps your cookies, cakes and sweet breads softer. Variances in sugar type will create different outcomes here.

What is the chemical reaction of sugar in baking? ›

During baking sugar, amino acids, peptides and proteins go through a process known as the Maillard Reaction. These reactions result in browning and produce wonderful smell associated with baked goods. The higher the sugar content, the darker golden brown the surface appears.

What is the science behind sugar in baking? ›

Sugar helps baked goods retain moisture.

This happens because sugar bonds with liquid in the recipe and retains that liquid. That bond helps keep baked good more moist (I know) for a longer period of time, increasing the shelf life of your baked goods!

What is the chemical formula for baking sugar? ›

C12H22O11 is the chemical or molecular formula for sucrose, meaning each sugar molecule contains 12 atoms of carbon, 22 atoms of hydrogen and 11 atoms of oxygen.

What is the chemical equation for baking cookies? ›

While baking, the heat allows for the sucrose (sugar) to break down into glucose and fructose. This causes a polymer chain which allows for the cookie to have a light brown, shiny crust. When the sodium bicarbonate (baking soda) absorbs heat, a chemical reaction occurs – 2NaHCO3 –> Na2CO3 + H2O + CO2.

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